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STM Investigation of Molecular Architectures of Porphyrinoids on a Ag(111) Surface: Supramolecular Ordering, Electronic Properties - new book

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The functionalization of surfaces on the nanoscale is one of the most fascinating and at the same time challenging topics in science. It is the key to tailoring catalysts, sensors, or dev… More...

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STM Investigation of Molecular Architectures of Porphyrinoids on a Ag(111) Surface Supramolecular Ordering, Electronic Properties and Reactivity - Buchner, Florian
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STM Investigation of Molecular Architectures of Porphyrinoids on a Ag(111) Surface Supramolecular Ordering, Electronic Properties and Reactivity - new book

2013, ISBN: 3642265952

2010 Kartoniert / Broschiert Analytische Chemie, Spektroskopie, Spektrochemie, Massenspektrometrie, Physikalische Chemie, Energietechnik, Elektrotechnik und Energiemaschinenbau, STEM; S… More...

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Buchner, Florian:
STM Investigation of Molecular Architectures of Porphyrinoids on a Ag(111) Surface Supramolecular Ordering, Electronic Properties and Reactivity - new book

2013

ISBN: 3642265952

2010 Kartoniert / Broschiert Analytische Chemie, Spektroskopie, Spektrochemie, Massenspektrometrie, Physikalische Chemie, Energietechnik, Elektrotechnik und Energiemaschinenbau, Stem; s… More...

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STM Investigation of Molecular Architectures of Porphyrinoids on a Ag(111) Surface - Paperback

2010, ISBN: 3642265952

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STM Investigation of Molecular Architectures of Porphyrinoids on a Ag(111) Surface - Florian Buchner
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STM Investigation of Molecular Architectures of Porphyrinoids on a Ag(111) Surface - Paperback

2013, ISBN: 9783642265952

Supramolecular Ordering, Electronic Properties and Reactivity, 2010, Softcover, Buch, [PU: Springer Berlin]

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Details of the book

Details of the book - STM Investigation of Molecular Architectures of Porphyrinoids on a Ag(111) Surface


EAN (ISBN-13): 9783642265952
ISBN (ISBN-10): 3642265952
Hardcover
Paperback
Publishing year: 2013
Publisher: Springer Berlin

Book in our database since 2014-02-19T10:42:58-05:00 (New York)
Detail page last modified on 2022-03-30T03:05:45-04:00 (New York)
ISBN/EAN: 9783642265952

ISBN - alternate spelling:
3-642-26595-2, 978-3-642-26595-2


Information from Publisher

Author: Florian Buchner
Title: Springer Theses; STM Investigation of Molecular Architectures of Porphyrinoids on a Ag(111) Surface - Supramolecular Ordering, Electronic Properties and Reactivity
Publisher: Springer; Springer Berlin
164 Pages
Publishing year: 2013-01-02
Berlin; Heidelberg; DE
Printed / Made in
Weight: 0,304 kg
Language: English
99,98 € (DE)
102,78 € (AT)
110,50 CHF (CH)
POD
XXVII, 164 p.

BC; Previously published in hardcover; Hardcover, Softcover / Chemie/Physikalische Chemie; Physikalische Chemie; Verstehen; Chemie; Porphyrinoids; STEM; STM; Scanning Tunneling Microscopy; Scanning Tunneling Spectroscopy; Self-assembly; Supra; Supramolecular Chemistry; Surface Chemistry; electronics; B; Physical Chemistry; Analytical Chemistry; Solid State Physics; Surface and Interface Science, Thin Films; Energy Systems; Physical Chemistry; Analytical Chemistry; Condensed Matter Physics; Surface and Interface and Thin Film; Electrical Power Engineering; Mechanical Power Engineering; Chemistry and Materials Science; Analytische Chemie; Physik der kondensierten Materie (Flüssigkeits- und Festkörperphysik); Physik der kondensierten Materie (Flüssigkeits- und Festkörperphysik); Elektrotechnik; Energietechnik, Elektrotechnik und Energiemaschinenbau; BB

1 Introduction ...................................................................................................... 1 2 Fundamentals .................................................................................................... 5 2.1 Principle of the STM ............................................................................................ 5 2.2 Origin of the Tunneling Current ........................................................................... 7 2.3 Scanning Tunneling Spectroscopy ...................................................................... 10 2.4 Contrast Mechanism of Molecular Adsorbates ................................................... 13 2.5 Temperature Programmed Desorption ................................................................ 16 2.6 Low Energy Electron Diffraction ....................................................................... 18 3 Experimental Setup ........................................................................................ 21 3.1 UHV System ...................................................................................................... 21 3.2 Scanning Tunneling Microscope ........................................................................ 23 3.3 Control Electronics and Vibration Isolation ........................................................ 26 3.4 Ag(111) ............................................................................................................. 28 3.5 Porphyrinoids..................................................................................................... 30 3.6 Preparation of thin Porphyrinoid Layers ............................................................. 33 3.7 Vapor-deposition of Cobalt and Iron .................................................................. 34 4 Results ............................................................................................................. 39 4.1 Self-Assembly and Individual Appearance of Tetraphenylporphyrins on Ag(111) ............................................................................................................. 41 4.1.1 Epitaxial growth ........................................................................................... 43 4.1.2 Appearance and Intramolecular Conformation .............................................. 48 4.1.3 Ordering Aspects.......................................................................................... 50 4.2 Self-Assembly and Individual Appearance of Cobalt(II)-Tetrakisditertbutylphenylporphyrins on Ag(111) ......................................................................... 61 4.2.1 Polymorphism of CoTTBPP ......................................................................... 62 4.2.2 Polarity-Dependent Appearance ................................................................... 78 ii Table of Contents 4.3 Coordination of Iron and Cobalt Atoms by Tetraphenylporphyrin Monolayers on Ag(111) and Formation of Metal(II)-Tetraphenylporphyrin ......... 83 4.3.1 Coordination of Post-deposited Iron Atoms by Tetraphenylporphyrin Monolayers ................................................................................................... 85 4.3.2 Coordination of Pre-deposited Iron Atoms by Tetraphenylporphyrin Monolayers ................................................................................................... 90 4.3.3 Coordination of Post-deposited Cobalt Atoms by Tetraphenylporphyrin Monolayers ................................................................................................... 94 4.3.4 Discussion of the Metalation Reaction .......................................................... 99 4.4 Different Aspects of 2H-Tetrakisditertbutylphenylporphyrin on Ag(111) .. 103 4.4.1 Monolayer Preparation................................................................................ 104 4.4.2 Arrangement of 2HTTBPP ......................................................................... 107 4

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